DOI: https://doi.org/10.29363/nanoge.hopv.2025.014
Publication date: 13th February 2026
In photovoltaics, perovskite-based solar cells constitute a special type of light-harvesting devices because, in addition to electronic mechanisms, the presence of moving ionic species is believed to modify current-voltage curves. Identification of specific operating mechanisms becomes particularly challenging when mixed ionic-electronic conductors are used in optoelectronic devices. Ionic effects in perovskite solar cells are believed to distort operation curves and possess serious doubts about their long term stability. Current hysteresis and switchable photovoltaic characteristics have been connected to the kinetics of ion migration. However, the nature of the specific ionic mechanism (or mechanisms) able to explain the operation distortions is still poorly understood. It is observed here that the local rearrangement of ions at the electrode interfaces gives rise to commonly observed capacitive effects.Charging transients in response to step voltage stimuli using thick CH3NH3PbI3 samples show two main polarization processes and reveal the structure of the ionic double-layer at the interface with the non-reacting contacts. It is observed that ionic charging, with a typical response time of 10 s, is a local effect confined in the vicinity of the electrode, which entails absence of net mobile iònic concentration (space-charge) in the material bulk
