Capacitance response by local imbalance at interfaces in hybrid lead halide perovskites.
MARISE GARCIA BATLLE a
a Institute of Advanced Materials, Universitat Jaume I, Spain, Av Sos Baynat s/n, Castelló, Castellón, 12006, Spain
Proceedings of International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (HOPV20)
Santa Fe, United States, 2025 September 8th - 10th
Organizers: test11 test11, test7 test7 and Organizer Two
Poster, MARISE GARCIA BATLLE, 014
DOI: https://doi.org/10.29363/nanoge.hopv.2025.014
Publication date: 13th February 2026

In photovoltaics, perovskite-based solar cells constitute a special type of light-harvesting devices because, in addition to electronic mechanisms, the presence of moving ionic species is believed to modify current-voltage curves. Identification of specific operating mechanisms becomes particularly challenging when mixed ionic-electronic conductors are used in optoelectronic devices. Ionic effects in perovskite solar cells are believed to distort operation curves and possess serious doubts about their long term stability. Current hysteresis and switchable photovoltaic characteristics have been connected to the kinetics of ion migration. However, the nature of the specific ionic mechanism (or mechanisms) able to explain the operation distortions is still poorly understood. It is observed here that the local rearrangement of ions at the electrode interfaces gives rise to commonly observed capacitive effects.Charging transients in response to step voltage stimuli using thick CH3NH3PbI3 samples show two main polarization processes and reveal the structure of the ionic double-layer at the interface with the non-reacting contacts. It is observed that ionic charging, with a typical response time of 10 s, is a local effect confined in the vicinity of the electrode, which entails absence of net mobile iònic concentration (space-charge) in the material bulk

 

© Fundació Scito
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info